Christiana, Rebecca and Miki, Takeshi and Kakitani, Yoshinori and Aoyagi, Shiho and Koyama, Yasushi and Limantara, Leenawaty (2009) Energies and Excited-State Dynamics of 1Bu+, 1Bu- and 3Ag- States of Carotenoids Bound to LH2 Antenna Complexes from Purple Photosynthetic Bacteria. Chemical Physics Letters, 480. pp. 298-295.
Full text not available from this repository. (Request a copy)Abstract
Time-resolved pump–probe stimulated-emission and transient-absorption spectra were recorded after excitation with ∼30 fs pulses to the 1Bu+(0) and optically-forbidden diabatic levels of carotenoids, neurosporene, spheroidene and lycopene having n = 9–11 double bonds, bound to LH2 antenna complexes from Rhodobacter sphaeroides G1C, 2.4.1 and Rhodospirillum molischianum. The low-energy shift of stimulated emission from the covalent 1Bu-(0) and 3Ag-(0) levels slightly larger than that from the ionic 1Bu+(0) state suggests the polarization, whereas more efficient triplet generation suggests the twisting of the conjugated chain in Cars bound to the LH2 complexes, when compared to Cars free in solution
| Item Type: | Artikel |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Fakultas Teknologi dan Desain > Teknik Sipil |
| Depositing User: | Admin Repository |
| Date Deposited: | 15 Apr 2020 10:47 |
| Last Modified: | 03 Jun 2022 01:40 |
| URI: | http://eprints.upj.ac.id/id/eprint/91 |
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